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高士祥

高士祥

教授

地址:南京大学环境学院C520室

电话:025-89680359

Email: ecsxg@nju.edu.cn


教育经历

1982. 7 华东石油学院炼制系本科毕业

1985. 8 中国科学院环境化学研究所硕士研究生毕业

1999. 7 南京大学环境学院博士研究生毕业


工作经历

2003年至今:南京大学环境学院教授,博士生导师

2013/6-2013/11:美国威斯康辛大学麦迪孙分校(The University of Wisconsin -Madison)土壤科学系高级访问学者

2006年-2013年:南京大学环境科学研究所副所长

2000-2008年:南京大学环境化学教研室主任

1999-2002年:南京大学环境学院副教授

1989-1991年:加拿大不列颠哥伦比亚大学(The University of British Columbia)化学系访问学者

1985-1999年:江苏省理化测试中心工程师、副研究员


研究领域有机污染化学

围绕有机污染物在环境中的迁移转化过程,主要开展有机污染物在水和土壤环境中的光降解、氧化/还原降解、生物降解等转化过程的机制研究,重点关注复杂环境因子的影响及多种过程的协同耦合机制。近期关注的污染物包括阻燃剂、药物、抗生素、雌激素、微塑料等新型污染物。


学术兼职

中国环境科学学会持久性有机污染物专业委员会委员

中国毒理学会环境与生态毒理学专业委员会委员

中国毒理学会计算毒理学专业委员会委员

江苏科技大学兼职教授

《环境化学》编委

《生态与农村环境学报》编委


课程教学

《大气雾霾污染与健康》本科生新生研讨课

《污染生态效应的化学机制》硕士研究生课程


科研项目

科技部,国家重点研发计划"场地土壤污染成因与治理技术"重点专项"复合有机污染场地原位热处理耦合修复技术与装备",2020/01-2023/12

2. 国家自然科学基金面上项目,微塑料老化过程及其环境行为与毒性变化的机理研究,2019/01-2022/12,主持

3. 国家自然科学基金面上项目,天然水体中自然光与过氧化物酶协同降解消毒剂类污染物的机理研究,2016/01-2019/12,主持

4. 国家自然科学基金面上项目,有机磷阻燃剂的鱼体代谢过程及其毒性效应的结构-活性关系,2014/01-2017/12,主持

5. 环保部环保公益性行业科研专项,化学工业废水处理污泥污染特征与污染风险控制研究,2015/04-2018/04,参加

6. 国家"973"项目,持久性有机污染物的环境行为、毒性效应与控制技术原理,课题4"POPs污染物的生物转移、累积与放大",2009.1-2013.12,参加

7. 环保部环保公益性行业科研专项,兽药污染的健康风险评估与风险管理技术研究,2011.1-2014.1,参加

8.国家自然科学基金项目,多溴联苯醚肝脏代谢机理的模拟研究,2010.1-2013.12,主持

9. 国家"863"重大项目,重大环境污染事件应急技术系统研究开发与应用示范"课题"重大环境污染事件风险场预警技术, 2007.12-2012.8,主持

10. 国家"十一五"国家水体污染控制与治理科技重大专项课题,流域水环境质量基准与标准体系研究课题,子课题"流域水生生物毒理学效应基准指标与基准阈值",2008.1-2011.12,参加

11. 国家自然科学基金项目,白腐菌降解多溴二苯醚的机理研究,2007.1-2009.12,主持

12.江苏省社会发展项目,大气污染对六朝石刻的影响及保护对策研究,2006.1-2008.12,主持

13.国家自然科学基金项目,环糊精促进难降解有机污染物生物降解研究,2001.1-2003.12,主持


代表性论文

Wang, Mengjie; Shi, Huanhuan; Shao, Shuai; Lu, Kun; Wang, Hanyu; Yang, Yun; Gong, Zhimin; Zuo, Yuegang; Gao, Shixiang*; Montmorillonite promoted photodegradation of amlodipine in natural water via formation of surface complexes, Chemosphere, 286(Pt 1):131641, 2021

Gong, ZM; Wang, GB; Shi, HH; Shao, S; Wang, MJ; Lu, KGao, SX*; Mn(II)-Mn(III)-Mn(IV) redox cycling inhibits the removal of methylparaben and acetaminophen mediated by horseradish peroxidase: New insights into the mechanism, Science of the Total Environment, 788:147788, 2021

Wu, Xiaowei; Liu, Peng; Wang, Hanyu; Huang, Hexinyue; Shi, Yanqi; Yang, Changfu; Gao, Shixiang*; Photo aging of polypropylene microplastics in estuary water and coastal seawater: Important role of chlorine ion, Water Research, 202:117396, 2021

Shi, Yanqi; Liu, Peng; Wu, Xiaowei; Shi, Huanhuan; Huang, Hexinyue; Wang, Hanyu; Gao, Shixiang*, Insight into chain scission and release profiles from photodegradation of polycarbonate microplastics, Water Research, 195:116980, 2021

Wang, Hanyu; Liu, Peng; Wang, Mengjie; Wu, Journal of Hazardous Materials, 408:124756, 2021

Wang, Mengjie; Xiang, Xueying; Zuo, Yuegang; Gao, Shixiang*; Singlet oxygen production abilities of oxidated aromatic compounds in natural water, Chemosphere, 258:127308, 2020

Liu, Peng; Wu, Xiaowei; Peng, Jianbiao; Wang, Hanyu; Shi, Yanqi; Huang, Hexinyue; Gao, Shixiang*, "Critical effect of iron red pigment on photoaging behavior of polypropylene microplastics in artificial seawater.", Journal of hazardous materials, 404(Pt B) :124209, 2020

Wu, Xiaowei; Liu, Peng; Shi, Huanhuan; Wang, Hanyu; Huang, Hexinyue; Shi, Yanqi; Gao, Shixiang*, "Photo aging and fragmentation of polypropylene food packaging materials in artificial seawater." Water research, 188:116456, 2020

Shi, Huanhuan; Wang, Mengjie; Wang, Beibei; Gao, Shixiang*; Insights on photochemical activities of organic components and minerals in dissolved state biochar in the degradation of atorvastatin in aqueous solution. Journal of Hazardous Materials, 392:122277, 2020

Liu, Peng; Wu, Xiaowei; Liu, Haiyong; Gao, Shixiang*; Desorption of pharmaceuticals from pristine and aged polystyrene microplastics under simulated gastrointestinal conditionsJournal of Hazardous Materials392122346, 2020

Wu, Xiaowei; Liu, Peng; Huang, Hexinyue; Gao, Shixiang*Adsorption of triclosan onto different aged polypropylene microplastics: Critical effect of cationsScience of the Total Environment717137033, 2020

Wang, Mengjie; Shi, Qinren; Shi, Huanhuan; Li, Jianhua; Yang, Yun ; Qian, Li; Shao, Shuai; Gao, Shixiang*The promotion effect of phenolic acid compound on the photo-removal of estrogen from water under simulated sunlight irradiation Chemical Engineering Journal387123999, 2020

Shuai Shao, Li Qian, Xin Zhan, Mengjie Wang, Shixiang Gao*, Transformation and toxicity evolution of amlodipine mediated by cobalt ferrite activated peroxymonosulfate: Effect of oxidant concentration, Chemical Engineering Journal, 382:123005, 2020

Gong, Zhimin; Yang, Yun; Wang, Mengjie; Lu, Kun; Liu, Peng; Wang, Hanyu; Gao, Shixiang*; Degradation of acetaminophen in photo-enzyme coupling system with natural organic matters from different sources, The Science of the total environment, 704: 135246, 2020

Liu, Peng; Zhan, Xin; Wu, Xiaowei; Li, Jinli; Wang, Hanyu; Gao, Shixiang*Effect of weathering on environmental behavior of microplastics: Properties, sorption and potential risks. Chemosphere, 242:125193, 2020

Liu, Peng; Lu, Kun; Li, Jinli; Wu, Xiaowei; Qian, Li; Wang, Mengjie; Gao, Shixiang*, Effect of aging on adsorption behavior of polystyrene microplastics for pharmaceuticals: Adsorption mechanism and role of aging intermediates, Journal of hazardous materials, 384:121193, 2020

Peng, JB; Zhang, CN; Zhang, Y; Miao, D; Zhang, YZ; Liu, HJ; Li, JH; Xu, L; Shi, JL; Liu, GG; Gao, SX*; Enhanced Cu(II)-mediated fenton-like oxidation of antimicrobials in bicarbonate aqueous solution: Kinetics, mechanism and toxicity evaluation", Environmental Pollution, 252: 1933-1941(B), 2019

Peng, JB; Zhang, YZ; Zhang, CN; Miao, D; Li, JH; Liu, HJ; Wang, LH; Gao, SX*, Removal of triclosan in a Fenton-like system mediated by graphene oxide: Reaction kinetics and ecotoxicity evaluation, Science of the Total Environment, 673: 726-733, 2019

Li Qian, Peng Liu, Shuai Shao, Mengjie Wang, Xin Zhan, Shixiang Gao*. An Efficient Graphene Supported Copper Salen Catalyst for the Activation of Persulfate to Remove Chlorophenols in Aqueous Solution. Chemical Engineering Journal., 360, 54-632019

Liu, Peng; Qian, Li; Wang, Hanyu; Zhan, Xin; Lu, Kun; Gu, Cheng*; Gao, Shixiang*, New Insights into the Aging Behavior of Microplastics Accelerated by Advanced Oxidation Processes, Environmental science & technology, 537: 3579-35882019

Wang, Mengjie; Li, Jianhua; Shi, Huanhuan; Miao, Dong; Yang, Yun; Qian, Li; Gao, Shixiang*; Photolysis of atorvastatin in aquatic environment: Influencing factors, products, and pathways, Chemosphere, 212: 467-475, 2018

Miao, Dong; Peng, Jianbiao; Zhou, Xiaohuan; Qian, Li; Wang, Mengjie; Zhai, Li; Gao, Shixiang*, Oxidative degradation of atenolol by heat-activated persulfate: Kinetics, degradation pathways and distribution of transformation intermediates, Chemosphere, 207: 174-182, 2018

Yang, Yun; Li, Jianhua; Shi, Huanhuan; Zhai, Li; Wang, Xing; Gao, Shixiang*, Influence of natural organic matter on horseradish peroxidase-mediated removal of 17 alpha- ethinylestradiol: Role of molecular weight, Journal of Hazardous Materials, 356: 9-16, 2018

Miao, Dong ; Peng, Jianbiao; Wang, Mengjie; Shao, Shuai; Wang, Lianhong; Gao, Shixiang*, Removal of atorvastatin in water mediated by CuFe2O4 activated peroxymonosulfate, Chemical Engineering Journal, 346:1-10, 2018

Shi, Huanhuan; Wang, Guowei; Huang, Qingguo; Li, Jianhua; Yang, Yun; Gao, Shixiang*; Wang, Zunyao, The mutual promotion of photolysis and laccase-catalysis on removal of dichlorophen from water under simulated sunlight irradiation, Chemical Engineering Journal, 338: 392-400, 2018

Hanyan Chen; Pingping Wang; Zhongkun Du; Guowei Wang; Shixiang Gao*, Oxidative stress, cell cycle arrest, DNA damage and apoptosis in adult zebrafish (Danio rerio) induced by tris(1,3-dichloro-2-propyl) phosphate, Aquatic Toxicology, 19437~45, 2018

Guowei Wang, Huanhuan Shi, Zhongkun Du, Hanyan Chen, Jianbiao Peng, Shixiang Gao*Bioaccumulation mechanism of organophosphate esters in adult zebrafish (Danio rerio)Environmental Pollution229:177–187, 2017

Yang, Yun; Li, Jianhua; Lu, Kun; Shi, Huanhuan; Gao, Shixiang*, Transformation of 17alpha-ethinylestradiol by simultaneous photo-enzymatic process in Humic water. Chemosphere, 178:432-438, 2017

Jianbiao Peng, Jie Xue, Jianhua Li, Zhongkun Du, Zunyao Wang, Shixiang Gao*, Catalytic effect of low concentration carboxylated multi-walled carbon nanotubes on the oxidation of disinfectants with Cl-substituted structure by a Fenton-like system, Chemical Engineering Journal, 321:325–334, 2017

Wang, Guowei; Chen, Hanyan; Du, Zhongkun; Li, Jianhua; Wang, Zunyao; Gao, Shixiang*, In vivo metabolism of organophosphate flame retardants and distribution of their main metabolites in adult zebrafish. The Science of the total environment590-591:50-592017

Feng, Yiping; Lu, Kun; Gao, Shixiang*; Mao, Liang*, The fate and transformation of tetrabromobisphenol A in natural waters, mediated by oxidoreductase enzymes. Environmental science. Processes & impacts, 19(4): 596-6042017

Jianhua Li, Ya Zhang, Qingguo Huang, Huanhuan Shi, Yun Yang, Shixiang Gao∗, Liang Mao, Xi YangDegradation of organic pollutants mediated by extracellular peroxidase in simulated sunlit humic waters: A case study with17beta-estradiolJournal of Hazardous Materials, 331123–1312017

Jianhua Li, Ya Zhang, Jianbiao Peng, Xinan Wu, Shixiang Gao*, Liang MaoThe effect of dissolved organic matter on soybean peroxidase-mediated removal of triclosan in waterChemosphere, 172:399-407, 2017

Wang, GW; Du, ZK; Chen, HY; Su, Y; Gao, SX∗; Mao, LTissue-Specific Accumulation, Depuration, and Transformation of Triphenyl Phosphate (TPHP) in Adult Zebrafish (Danio rerio)Environmental science & technology5024: 13555-135642016

Peng, Jianbiao; Shi, Huanhuan; Li, JianhuaWang, LHWang, ZY; Gao, SX*Bicarbonate enhanced removal of triclosan by copper(II) catalyzed Fenton-like reaction in aqueous solutionChemical Engineering Journal306: 484-4912016

Wang, Pingping; Du, Zhongkun; Gao, Shixiang*; Zhang, XW*; Giesy, JPImpairment of reproduction of adult zebrafish (Danio rerio) by binary mixtures of environmentally relevant concentrations of triclocarban and inorganic mercuryEcotoxicology and Environmental Safety134: 124-1322016

Shi, HH; Peng, JB; Li, JH; Mao, L; Wang, ZY; Gao, SX*; Laccase-catalyzed removal of the antimicrobials chlorophene and dichlorophen from water: Reaction kinetics, pathway and toxicity evaluationJournal of Hazardous Materials317: 81-892016

Dong, SP; Xiao, HF; Huang, QG; Zhang, J; Mao, L*; Gao, SX*Graphene Facilitated Removal of Labetalol in Laccase-ABTS System: Reaction Efficiency, Pathways and MechanismScientific Reports 6: 21396, 2016

Du ZK, Zhang Y, Wang GW, Peng JB, Wang ZY, Gao SX*. TPhP exposure disturbs carbohydrate metabolism, lipid metabolism, and the DNA damage repair system in zebrafish liver. Scientific Reports. 6:21827DOI: 10.1038/srep218272016.

Li JH, Zhang Y, Du ZK, Peng JB, Mao L, Gao SX*. Biotransformation of OH-PBDEs by pig liver microsomes: Investigating kinetics, identifying metabolites, and examining the role of different CYP isoforms. Chemosphere. 148: 354-360, 2016.

Li JH, Peng JB, Zhang Y, Ji YF, Shi HH, Mao L, Gao SX*. Removal of triclosan via peroxidases-mediated reactions in water: Reaction kinetics, products and detoxification. Journal of Hazardous Materials. 310: 152–160, 2016.

Peng JB, Li JH, Shi HH, Wang ZY, Gao SX*. Oxidation of disinfectants with Cl-substituted structure by a Fenton-like system Cu2+/H2O2 and analysis on their structure-reactivity relationship, Environ. Sci. Pol. Res. 23:1898–1904, 2016

Kan Haifeng; Zhao Fuzheng; Zhang Xu-Xiang*; Ren Hongqiang; Gao Shixiang* Correlations of Gut Microbial Community Shift with Hepatic Damage and Growth Inhibition of Carassius auratus Induced by Pentachlorophenol ExposureEnvironmental science & technology4919: 11894-119022015

Du Zhongkun; Wang Guowei; Gao Shixiang*; Wang ZunyaoAryl organophosphate flame retardants induced cardiotoxicity during zebrafish embryogenesis: By disturbing expression of the transcriptional regulatorsAquatic Toxicology1611: 25-322015.


授权发明专利

一种降解氯酚类污染物的催化剂、制备方法和应用,发明人:高士祥,钱力,邵帅;专利号:ZL2018 1 0050114.5


科技奖励

1. 养殖业中抗生素的环境影响及风险评估技术研究,环境保护部环境保护科学技术奖,二等奖,2017.12

2. 新型污染物的环境过程机制及其结构-活性关系的研究,教育部高等学校科学研究优秀成果奖-自然科学奖, 二等奖,2012.12

3. 有毒有机物结构与作用机理的研究,教育部自然科学奖,二等奖,2002.12


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