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高士祥
教授
地址：南京大学环境学院C520室
Email: ecsxg@nju.edu.cn
教育经历
1982.7 华东石油学院炼制系本科毕业
1985.8 中国科学院环境化学研究所硕士研究生毕业
1999.7 南京大学环境学院博士研究生毕业
工作经历
2003年至今：南京大学环境学院教授，博士生导师
2013/6-2013/11：美国威斯康辛大学麦迪孙分校（The University of Wisconsin -Madison）土壤科学系高级访问学者
2006-2013年：南京大学环境科学研究所副所长
2000-2008年：南京大学环境化学教研室主任
1999-2002年：南京大学环境学院副教授
1989-1991年：加拿大不列颠哥伦比亚大学（The University of British Columbia）化学系访问学者
1985-1999年：江苏省理化测试中心工程师、副研究员
研究领域：有机污染化学
围绕有机污染物在环境中的迁移转化过程，主要开展有机污染物在水和土壤环境中的光降解、氧化/还原降解、生物降解等转化过程的机制研究，重点关注复杂环境因子的影响及多种过程的协同耦合机制。近期关注的污染物包括阻燃剂、药物、抗生素、雌激素、微塑料等新型污染物。
学术兼职
中国环境科学学会持久性有机污染物专业委员会委员
中国毒理学会环境与生态毒理学专业委员会委员
中国毒理学会计算毒理学专业委员会委员
《生态与农村环境学报》编委
课程教学
《大气雾霾污染与健康》本科生新生研讨课
《污染生态效应的化学机制》硕士研究生课程
科研项目
1. 国家自然科学基金专项项目，环境中微塑料的检测新方法与污染特征，2023/01-2026/12，主持
2. 科技部，国家重点研发计划“场地土壤污染成因与治理技术”重点专项“复合有机污染场地原位热处理耦合修复技术与装备”，2020/01-2023/12，参加
3. 国家自然科学基金面上项目，微塑料老化过程及其环境行为与毒性变化的机理研究，2019/01-2022/12，主持
4. 国家自然科学基金面上项目，天然水体中自然光与过氧化物酶协同降解消毒剂类污染物的机理研究，2016/01-2019/12，主持
5. 国家自然科学基金面上项目，有机磷阻燃剂的鱼体代谢过程及其毒性效应的结构-活性关系，2014/01-2017/12，主持
6. 环保部环保公益性行业科研专项，化学工业废水处理污泥污染特征与污染风险控制研究，2015/04-2018/04，参加
7. 国家“973”项目，持久性有机污染物的环境行为、毒性效应与控制技术原理，课题4“POPs污染物的生物转移、累积与放大”，2009/1-2013/12，参加
8. 环保部环保公益性行业科研专项，兽药污染的健康风险评估与风险管理技术研究，2011.1-2014.1，参加
9.国家自然科学基金项目，多溴联苯醚肝脏代谢机理的模拟研究，2010/1-2013/12，主持
10. 国家“863”重大项目，重大环境污染事件应急技术系统研究开发与应用示范”课题“重大环境污染事件风险场预警技术， 2007/12-2012/8，主持
11. 国家自然科学基金项目，白腐菌降解多溴二苯醚的机理研究，2007/1-2009.12，主持
12. 江苏省社会发展项目，大气污染对六朝石刻的影响及保护对策研究，2006/1-2008/12，主持
13. 国家自然科学基金项目，环糊精促进难降解有机污染物生物降解研究，2001/1-2003/12，主持
代表性论文
1. Shi, Yanqi; Zheng, Lezhou; Huang, Hexinyue; Tian, Ye-Chao; Gong, Zhimin; Liu, Peng; Wu, Xiaowei; Li, Wen-Tao; Gao, Shixiang*, Formation of Nano- and Microplastics and Dissolved Chemicals During Photodegradation of Polyester Base Fabrics with Polyurethane Coating, Environmental science & technology, 57(5):1894-1906, DOI10.1021/acs.est.2c05063, FEB 7 2023
2. Shao, Shuai; Li, Xiaoshuai; Gong, Zhimin; Fan, Bo; Wang, Mengjie; Peng, Jianbiao; Lu, Kun*; Gao, Shixiang*; High efficiency activation of peroxydisulfate by an Fe3O4@PDAn-CuxO core-shell composite for triclosan degradation: The role of oxygen vacancy, Chemical Engineering Journal, 461:141719, DOI10.1016/j.cej.2023.141719, APR 1 2023
3. Fan, Bo; Li, Xiaoshuai; Zhu, Fengxiao; Wang, Jiahao; Gong, Zhimin; Shao, Shuai; Wang, Xiaonan; Zhu, Changyin*; Zhou, Dongmei; Gao, Shixiang*; Anti-passivation ability of sulfidated microscale zero valent iron and its application for 1,1,2,2-tetrachloroethane degradation, Journal of hazardous materials, 443PartA:130194, DOI10.1016/j.jhazmat.2022.130194, FEB 5 2023
4. Gong, Zhimin; Qian, Li; Shao, Shuai; Fan, Bo; Peng, Jianbiao; Lu, Kun*; Gao, Shixiang*; Effects of solvent composition on the synthesis of polydopamine Schiff base Cu complex to activate peroxymonosulfate for methyl-paraben degradation, Chemical Engineering Journal, 436:135034, DOI10.1016/j.cej.2022.135034, MAY 15 2022
5. Gong, Zhimin; Wang, Gaobo; Shao, Shuai; Wang, Mengjie; Lu, Kun*; Gao, Shixiang*; Co-degradation of coexisting pollutants methylparaben (mediators) and amlodipine in enzyme-mediator systems: Insight into the mediating mechanism, Journal of hazardous materials, 423:127112, DOI10.1016/j.jhazmat.2021.127112, FEB 5 2022
6. Shao, Shuai; Li, Xiaoshuai; Gong, Zhimin; Fan, Bo; Hu, Jianhua; Peng, Jianbiao; Lu, Kun*; Gao, Shixiang*; A new insight into the mechanism in Fe3O4@CuO/PMS system with low oxidant dosage, Chemical Engineering Journal, 438:135474, DOI10.1016/j.cej.2022.135474, JUN 15 2022
7. 吴小伟, 黄何欣悦, 石妍琦, 刘鹏, 王晗钰, 高士祥*，水环境中微塑料的光老化过程及影响因素研究进展，科学通报，66（36）: 4619 ~ 4632，doi: 10.1360/TB-2021-0376，2021-12-30
8. Wu, Xiaowei; Liu, Peng; Gong, Zhimin; Wang, Hanyu; Huang, Hexinyue; Shi, Yanqi; Zhao, Xiaoli; Gao, Shixiang*; Humic Acid and Fulvic Acid Hinder Long-Term Weathering of Microplastics in Lake Water, Environmental science & technology, 55(23): 15810-15820, 2021-12-07.
9. Wu, Xiaowei; Liu, Peng; Shi, Huanhuan; Wang, Hanyu; Huang, Hexinyue; Shi, Yanqi; Gao, Shixiang*, “Photo aging and fragmentation of polypropylene food packaging materials in artificial seawater.” Water research, 188:116456, Jan 1 2021
10. Wu, Xiaowei; Liu, Peng; Wang, Hanyu; Huang, Hexinyue; Shi, Yanqi; Yang, Changfu; Gao, Shixiang*; Photo aging of polypropylene microplastics in estuary water and coastal seawater: Important role of chlorine ion, Water Research, 202:117396, 2021
11. Shi, Yanqi; Liu, Peng; Wu, Xiaowei; Shi, Huanhuan; Huang, Hexinyue; Wang, Hanyu; Gao, Shixiang*, Insight into chain scission and release profiles from photodegradation of polycarbonate microplastics, Water Research, 195:116980, 2021
12. Shao, Shuai；Wang, Gaobo；Gong, Zhimin；Wang, Mengjie；Hu, Jianhua；Peng, Jianbiao；Lu, Kun*；Gao, Shixiang*；Insights into the role of hydroxyl group on carboxyl-modified MWCNTs in accelerating atenolol removal by Fe(III)/H2O(2) system, Chemical Engineering Journal, 425:130581, DOI10.1016/ j.cej.2021.130581, DEC 1 2021
13. Wang, Hanyu; Liu, Peng; Wang, Mengjie; Wu, Xiaowei; Shi, Yanqi; Huang, Hexinyue; Gao, Shixiang*, Enhanced phototransformation of atorvastatin by polystyrene microplastics: Critical role of aging, Journal of hazardous materials, 408:124756, DOI10.1016/j.jhazmat.2020.124756, APR 15 2021
14. Liu, Peng; Wu, Xiaowei; Peng, Jianbiao; Wang, Hanyu; Shi, Yanqi; Huang, Hexinyue; Gao, Shixiang*, “Critical effect of iron red pigment on photoaging behavior of polypropylene microplastics in artificial seawater.”, Journal of hazardous materials, 404(Pt B) :124209, FEB 15 2021
15. Shi, Huanhuan; Wang, Mengjie; Wang, Beibei; Gao, Shixiang*; Insights on photochemical activities of organic components and minerals in dissolved state biochar in the degradation of atorvastatin in aqueous solution. Journal of Hazardous Materials, 392:122277, 2020
16. Liu, Peng; Wu, Xiaowei; Liu, Haiyong; Gao, Shixiang*; Desorption of pharmaceuticals from pristine and aged polystyrene microplastics under simulated gastrointestinal conditions，Journal of Hazardous Materials，392：122346, 2020
17. Wang, Mengjie; Shi, Qinren; Shi, Huanhuan; Li, Jianhua; Yang, Yun ; Qian, Li; Shao, Shuai; Gao, Shixiang*；The promotion effect of phenolic acid compound on the photo-removal of estrogen from water under simulated sunlight irradiation， Chemical Engineering Journal，387：123999, 2020
18. Shuai Shao, Li Qian, Xin Zhan, Mengjie Wang, Shixiang Gao*, Transformation and toxicity evolution of amlodipine mediated by cobalt ferrite activated peroxymonosulfate: Effect of oxidant concentration, Chemical Engineering Journal, 382:123005, 2020
19. Liu, Peng; Lu, Kun; Li, Jinli; Wu, Xiaowei; Qian, Li; Wang, Mengjie; Gao, Shixiang*, Effect of aging on adsorption behavior of polystyrene microplastics for pharmaceuticals: Adsorption mechanism and role of aging intermediates, Journal of hazardous materials, 384:121193, 2020
20. Liu, Peng; Qian, Li; Wang, Hanyu; Zhan, Xin; Lu, Kun; Gu, Cheng*; Gao, Shixiang*, New Insights into the Aging Behavior of Microplastics Accelerated by Advanced Oxidation Processes, Environmental science & technology, 53（7）: 3579-3588，2019
21. Li Qian, Peng Liu, Shuai Shao, Mengjie Wang, Xin Zhan, Shixiang Gao*. An Efficient Graphene Supported Copper Salen Catalyst for the Activation of Persulfate to Remove Chlorophenols in Aqueous Solution. Chemical Engineering Journal., 360, 54-63，2019
22. Yang, Yun; Li, Jianhua; Shi, Huanhuan; Zhai, Li; Wang, Xing; Gao, Shixiang*, Influence of natural organic matter on horseradish peroxidase-mediated removal of 17 alpha- ethinylestradiol: Role of molecular weight, Journal of Hazardous Materials, 356: 9-16, 2018
23. Miao, Dong ; Peng, Jianbiao; Wang, Mengjie; Shao, Shuai; Wang, Lianhong; Gao, Shixiang*, Removal of atorvastatin in water mediated by CuFe2O4 activated peroxymonosulfate, Chemical Engineering Journal, 346:1-10, 2018
24. Shi, Huanhuan; Wang, Guowei; Huang, Qingguo; Li, Jianhua; Yang, Yun; Gao, Shixiang*; Wang, Zunyao, The mutual promotion of photolysis and laccase-catalysis on removal of dichlorophen from water under simulated sunlight irradiation, Chemical Engineering Journal, 338: 392-400, 2018
25. Hanyan Chen; Pingping Wang; Zhongkun Du; Guowei Wang; Shixiang Gao*, Oxidative stress, cell cycle arrest, DNA damage and apoptosis in adult zebrafish (Danio rerio) induced by tris(1,3-dichloro-2-propyl) phosphate, Aquatic Toxicology, 194：37~45, 2018
26. Jianbiao Peng, Jie Xue, Jianhua Li, Zhongkun Du, Zunyao Wang, Shixiang Gao*, Catalytic effect of low concentration carboxylated multi-walled carbon nanotubes on the oxidation of disinfectants with Cl-substituted structure by a Fenton-like system, Chemical Engineering Journal, 321:325–334, 2017
27. Jianhua Li, Ya Zhang, Qingguo Huang, Huanhuan Shi, Yun Yang, Shixiang Gao∗, Liang Mao, Xi Yang；Degradation of organic pollutants mediated by extracellular peroxidase in simulated sunlit humic waters: A case study with17beta-estradiol，Journal of Hazardous Materials, 331：123–131，2017
28. Wang, GW; Du, ZK; Chen, HY; Su, Y; Gao, SX∗; Mao, L；Tissue-Specific Accumulation, Depuration, and Transformation of Triphenyl Phosphate (TPHP) in Adult Zebrafish (Danio rerio)，Environmental science & technology，50（24）: 13555-13564，2016
29. Peng, Jianbiao; Shi, Huanhuan; Li, Jianhua；Wang, LH；Wang, ZY; Gao, SX*；Bicarbonate enhanced removal of triclosan by copper(II) catalyzed Fenton-like reaction in aqueous solution，Chemical Engineering Journal，306: 484-491，2016
30. Shi, HH; Peng, JB; Li, JH; Mao, L; Wang, ZY; Gao, SX*; Laccase-catalyzed removal of the antimicrobials chlorophene and dichlorophen from water: Reaction kinetics, pathway and toxicity evaluation，Journal of Hazardous Materials，317: 81-89，2016
31. Li JH, Peng JB, Zhang Y, Ji YF, Shi HH, Mao L, Gao SX*. Removal of triclosan via peroxidases-mediated reactions in water: Reaction kinetics, products and detoxification. Journal of Hazardous Materials. 310: 152–160, 2016.
32. Kan Haifeng; Zhao Fuzheng; Zhang Xu-Xiang*; Ren Hongqiang; Gao Shixiang*， Correlations of Gut Microbial Community Shift with Hepatic Damage and Growth Inhibition of Carassius auratus Induced by Pentachlorophenol Exposure，Environmental science & technology，49（19）: 11894-11902，2015
33. Du Zhongkun; Wang Guowei; Gao Shixiang*; Wang Zunyao，Aryl organophosphate flame retardants induced cardiotoxicity during zebrafish embryogenesis: By disturbing expression of the transcriptional regulators，Aquatic Toxicology，161（1）: 25-32，2015.
授权发明专利
1. 一种聚多巴胺席夫碱-铜配合物催化剂及其制备方法与应用, 发明人：高士祥，龚志敏，邵帅；专利号：ZL202111385321.4
2. 一种降解氯酚类污染物的催化剂、制备方法和应用，发明人：高士祥，钱力，邵帅；专利号：ZL2018 1 0050114.5
科技奖励
1. 应用放射性同位素示踪技术研究石墨烯的生物过程和食物链传输机制，教育部高等学校科学研究技术成果奖-自然奖，二等奖，2022年
2. 养殖业中抗生素的环境影响及风险评估技术研究，环境保护部环境保护科学技术奖，二等奖，2017.12
3. 新型污染物的环境过程机制及其结构-活性关系的研究，教育部高等学校科学研究优秀成果奖-自然科学奖, 二等奖，2012.12
4. 有毒有机物结构与作用机理的研究，教育部自然科学奖，二等奖，2002.12
